GLASS-FIBER CATALYSTS FOR SELECTIVE CATALYTIC REDUCTION OF NITROGEN OXIDES BY CO AND HYDROCARBONS

Glass-fiber catalysts for selective catalytic reduction of nitrogen oxides by CO and hydrocarbons

Glass-fiber catalysts for selective catalytic reduction of nitrogen oxides by CO and hydrocarbons

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Panel Kits Glass-fiber catalysts (GFCs) are investigated in the process of the catalytic reduction of nitrogen oxides by hydrocarbons and carbon monoxide contained in waste and flue gases.Studies show that the platinum-based GFCs prepared by surface high-temperature synthesis approach demonstrates higher activity in the reactions of NOx reduction and CO and CxHy oxidation, in comparison with conventional GFCs and catalytic systems based on oxides of MnCe and FeV.Structured cartridges with a corrugated and flat metal mesh with longitudinal flow direction and satin type GFC were found to provide the highest apparent catalyst activity.The kinetic Collections model for Pt/GFC was proposed based on the experimental data.

The best kinetic description is provided under account of formation of nitrite-nitrate surface compounds resulting from NO chemisorption and further interaction of these compounds with CO, as well as under account of simultaneous catalytic and non-catalytic oxidation of propane by oxygen both to CO and CO2.The proposed model may adequately reproduce the non-trivial experimental regularities, such as CO and NO conversion decrease at high temperatures and synergetic effect of oxygen on the rate of NO reduction by CO.

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